Name | Phosphorouspentabromide |
Synonyms | PHOSPHORIC BROMIDE PHOSPHORUS BROMIDE Phosphorus(V) bromide PHOSPHORUS PERBROMIDE Pentabromo phosphorus PHOSPHORIC (V) BROMIDE PHOSPHORUS (V) BROMIDE Phosphorouspentabromide Phosphorus pentabromide PHOSPHORUS PENTABROMIDE PHOSPHOROUS (V) BROMIDE pentabromo-lambda~5~-phosphane |
CAS | 7789-69-7 |
EINECS | 232-186-6 |
InChI | InChI=1/Br5P/c1-6(2,3,4)5 |
InChIKey | QRKVRHZNLKTPGF-UHFFFAOYSA-N |
Molecular Formula | Br5P |
Molar Mass | 430.49 |
Density | 3.610 |
Melting Point | 105-107°C (dec.) |
Boling Point | 105-107°C |
Flash Point | 105-107°C |
Water Solubility | Reacts with water. |
Appearance | yellow orthorhombic crystals |
Merck | 14,7350 |
BRN | 3903332 |
Sensitive | Moisture Sensitive |
Physical and Chemical Properties | Yellow crystals. Melting point 106 °c (decomposition). The chemical properties are similar to those of phosphorus pentachloride. When water or alcohol decomposition, soluble in benzene, carbon disulfide and carbon tetrachloride. |
Hazard Symbols | C - Corrosive |
Risk Codes | R14 - Reacts violently with water R34 - Causes burns |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
UN IDs | UN 2691 8/PG 2 |
WGK Germany | 3 |
TSCA | Yes |
HS Code | 28129000 |
Hazard Class | 8 |
Packing Group | II |
yellow crystals. Melting point 1 06 C (decomposition). The chemical properties are similar to those of phosphorus pentachloride. When water or alcohol decomposition, soluble in benzene, carbon disulfide and carbon tetrachloride.
phosphorus tribromide and a slight excess of bromine were reacted in carbon disulfide to form a crystalline substance, which was separated from the solvent. Using nitrobenzene as solvent for recrystallization, after filtration, the phosphorus pentabromide product was obtained.
organic synthetic brominating agents.
risk code: acid corrosion product. GB8.1 class 81057aUN NO, 2691; IMDG Code page 8207, class 8.1. Glass bottle packaging, each bottle of 0. 5kg net weight, and then concentrated in the wooden box village bedding. Large glass bottle net weight 2 5 kg. There are obvious signs of "drug" and "corrosion" on the package. Store in a cool, dry, ventilated warehouse. Packaging should be sealed and moisture-proof. It cannot be stored and mixed with flammable materials, organic materials, oxidants, alkaline materials and deliquescent materials. Transport should be protected from rain and sun. Handling should be light and light to prevent damage to the container. Fire, with dry sand, dry powder fire or carbon dioxide fire extinguishing, but not water. Toxicity and protection: see phosphorus trichloride.
EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
toxicity | see phosphorus trichloride. |
Use | organic synthesis. Brominating agent. |
production method | phosphorus tribromide and a slight excess of bromine are reacted in carbon disulfide to form a crystalline substance, which is separated from the solvent. Using nitrobenzene as solvent for recrystallization, after filtration, the phosphorus pentabromide product was obtained. PBr3 Br2 → PBr5 |